Topic: Solubility and Solubility Curves – Calculations and Interpretation
Class: SS1
Specific Objectives:
By the end of the lesson, students should be able to:
- Define solubility and saturated solutions.
- Explain factors affecting solubility.
- Interpret solubility curves.
- Calculate solubility of substances from experimental data.
- Apply solubility concepts in real-life situations.
Instructional Materials:
- Beakers, measuring cylinders
- Solids like potassium nitrate or copper(II) sulfate
- Thermometer
- Graph paper
- Pre-drawn solubility curves
- Stirring rods, balance, water bath
Lesson Content:
Step 1: Meaning of Solubility
Solubility is defined as the maximum amount of solute that can dissolve in 100 g of solvent (usually water) at a specific temperature to form a saturated solution.
Saturated solution: A solution in which no more solute can dissolve at a given temperature.
Step 2: Factors Affecting Solubility
-
Temperature:
- For most solids, solubility increases with temperature.
- For gases, solubility decreases as temperature increases.
-
Pressure:
- Affects solubility of gases (solubility increases with pressure).
-
Nature of solute and solvent:
- “Like dissolves like” – polar solutes dissolve in polar solvents.
Step 3: Interpreting Solubility Curves
A solubility curve is a graph that shows how the solubility of a substance changes with temperature.
How to read a solubility curve:
- Point on the curve: Saturated solution
- Point below the curve: Unsaturated solution
- Point above the curve: Supersaturated solution
Example:
If the curve of KNO₃ shows that 40 g dissolves in 100 g of water at 30°C, then:
- 35 g at 30°C → Unsaturated
- 45 g at 30°C → Supersaturated
Step 4: Sample Calculations
Example 1:
Find the solubility of potassium nitrate if 15 g dissolves in 50 g of water at 40°C.
Solution:
Convert to solubility per 100 g of water:
\frac{15}{50} \times 100 = 30 \, \text{g per 100 g of water}
Example 2:
From a solubility curve, 60 g of salt dissolves at 60°C, but only 40 g dissolves at 30°C. How much salt crystallizes out if the solution cools from 60°C to 30°C?
Solution:
60 g − 40 g = 20 g crystallizes
Step 5: Practical Applications of Solubility
- Pharmaceuticals: Correct drug dosage requires knowledge of solubility.
- Food industry: Sugar and salt dissolution.
- Environmental science: Solubility affects pollution and water purification.
- Crystallization: Used to purify solids in chemistry labs.
Evaluation:
- Define solubility.
- What is a saturated solution?
- How does temperature affect the solubility of solids?
- Describe how to read a solubility curve.
- If 25 g of salt dissolves in 50 g of water at a certain temperature, what is its solubility per 100 g of water?
Homework:
- Plot a solubility curve from the following data:
Temperature (°C) |
20 |
30 |
40 |
50 |
60 |
Solubility (g/100g H₂O) |
10 |
15 |
20 |
30 |
40 |
-
From the graph, answer:
a. What is the solubility at 45°C?
b. At what temperature does the solubility equal 25 g?
-
Explain what happens when a saturated solution is cooled.
Conclusion:
Solubility and solubility curves are important for understanding how substances dissolve in solvents under various conditions. This knowledge is applied in industries, laboratories, and even in daily life.
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