Topic: Solubility and Crystallization – Saturated Solutions, Solubility Curves
Class: SS1
Specific Objectives:
By the end of the lesson, students should be able to:
- Define solubility and saturated solution.
- Describe the process of crystallization.
- Interpret a solubility curve.
- Explain how temperature affects solubility.
- Carry out simple experiments involving crystallization.
Instructional Materials:
- Beakers or glass containers
- Common salt, sugar, copper(II) sulphate
- Water
- Heat source (Bunsen burner or spirit lamp)
- Stirring rod
- Thermometer
- Graph/chart paper showing solubility curves
Lesson Content:
Step 1: Definition of Solubility and Saturated Solution
- Solubility is the amount of solute that can dissolve in a given amount of solvent (usually 100 g of water) at a specific temperature to form a saturated solution.
- A saturated solution is one in which no more solute can dissolve at a given temperature.
Example:
If 36 g of NaCl dissolves in 100 g of water at 25°C, then the solubility of NaCl at 25°C is 36 g/100 g water.
Step 2: Crystallization
Crystallization is the process of forming solid crystals from a solution when the solute becomes more than the solvent can hold (usually by cooling or evaporating the solution).
Steps in Crystallization:
- Prepare a saturated solution of a solute (e.g., copper(II) sulphate) by dissolving it in hot water.
- Filter to remove impurities.
- Allow the hot saturated solution to cool slowly.
- Crystals will form as the solubility of the solute decreases with temperature.
Step 3: Solubility Curves
A solubility curve is a graph showing the relationship between solubility (Y-axis) and temperature (X-axis).
Reading a Solubility Curve:
- The curve shows how much solute dissolves at different temperatures.
- The higher the point on the curve, the more soluble the substance.
- If a solution contains more solute than the curve indicates, it is supersaturated.
Interpretation Example:
- At 20°C, 32 g of KNO₃ dissolves in 100 g water.
- At 60°C, about 110 g of KNO₃ dissolves in the same amount of water, showing that solubility increases with temperature.
Step 4: Factors Affecting Crystallization
- Cooling rate: Slow cooling gives larger, purer crystals.
- Purity of solute: Impurities prevent orderly crystal formation.
- Evaporation: Gradual evaporation of solvent leads to crystal formation.
Evaluation:
- Define the term solubility.
- What is a saturated solution?
- Describe the process of crystallization with an example.
- What does a solubility curve show?
- State two factors that affect the formation of crystals.
Homework:
- Sketch a solubility curve for potassium nitrate and describe the trend.
- List the differences between saturated and unsaturated solutions.
- Carry out a home experiment: Dissolve sugar in hot water, cool it, and describe what you observe after 24 hours.
- Write short notes on supersaturated and unsaturated solutions with examples.
Conclusion:
Solubility and crystallization are essential concepts in chemistry and industry. They help in purifying substances, manufacturing salts, and understanding how substances behave in solutions. Crystallization, in particular, is a useful technique for obtaining pure solid compounds.
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